Equal quantities (50 ml) of the following four samples of water are placed in four beakers of 100 ml capacity. Their boiling points are determined accurately using the same thermometer. Which sample of water will have the lowermost boiling point as compared to other three samples?

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Equal quantities (50 ml) of the following four samples of water are placed in four beakers of 100 ml capacity. Their boiling points are determined accurately using the same thermometer. Which sample of water will have the lowermost boiling point as compared to other three samples?