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Typically - the isotopic substitution is made with an atom that takes part in the reaction. This will produce a primary isotope effect. If the substitution is made with an atom that does not directly participate in the reaction - a secondary isotope

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1. Typically - the isotopic substitution is made with an atom that takes part in the reaction. This will produce a primary isotope effect. If the substitution is made with an atom that does not directly participate in the reaction - a secondary isotope





 
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