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Study Guide: Hazard Communication: SDS, Labels, and Employee Right-to-Know Traps
Source: https://www.fatskills.com/osha-standards/chapter/hazard-communication-sds-labels-and-employee-right-to-know-traps

Hazard Communication: SDS, Labels, and Employee Right-to-Know Traps

By Fatskills Exam Guides Team — the exam nerds behind 28,500+ quizzes and 2.1M practice questions across 500+ global exams.

⏱️ ~2 min read

29 CFR 1910.1200 · Hazard Communication Standard (HCS 2012 / GHS-aligned)

Keywords: hazard communication standard, SDS sections, GHS labels, pictograms OSHA, right-to-know training, signal words, chemical inventory, secondary container labeling

The 16 SDS Sections — Must-Know Numbers

# Section Title
1 Identification
2 Hazard Identification
3 Composition / Ingredients
4 First-Aid Measures
5 Fire-Fighting Measures
6 Accidental Release Measures
7 Handling and Storage
8 Exposure Controls / Personal Protection
9 Physical and Chemical Properties
10 Stability and Reactivity
11 Toxicological Information
12–16 Ecotox, Disposal, Transport, Regulatory, Other

GHS Label — 6 Required Elements

  • Product identifier: chemical name or number
  • Signal word: "Danger" (more severe) or "Warning" (less severe)
  • Hazard statements: standardized phrases describing the nature of the hazard
  • Precautionary statements: how to minimize or prevent exposure/injury
  • Pictogram(s): GHS symbol in red diamond border
  • Supplier identification: name, address, phone of manufacturer/importer

Exam Traps — HazCom

  • Employees must be trained before their initial assignment to work with hazardous chemicals — not within 30 days of hire.
  • Secondary containers (e.g., a smaller pour bottle) require labeling unless used by the same person during the same work shift and the contents are clear.
  • SDSs must be readily accessible to employees during the work shift — locked in a filing cabinet does not meet the standard.
  • The written HazCom program must list all hazardous chemicals in each work area — an SDS binder alone is not a substitute for the written program.
  • "Warning" and "Danger" are not interchangeable. "Danger" = higher hazard category. Mixing them up is a common distractor.
  • Employers must maintain SDSs for each chemical; they cannot simply reference the chemical manufacturer's website as the sole access method.

GHS Pictograms — What They Cover

Pictogram Hazard Class
Flame Flammables, pyrophorics, self-heating
Exclamation mark Irritant, skin/eye sensitizer, acute tox (cat 4/5)
Skull & crossbones Acute toxicity (cat 1–3)
Corrosion Skin/eye corrosives, corrosive to metals
Health hazard Carcinogens, reproductive tox, STOT, mutagenicity
Gas cylinder Gases under pressure
Exploding bomb Explosives, self-reactives, organic peroxides
Flame over circle Oxidizers
Environment Aquatic toxicity (non-mandatory in US)


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