Kinetics
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Kinetics
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20 Questions

1. The units of the rate constant (k) for a reaction that occurs between two second-order reactants is:
2. Properties of a catalyst include all of the following except:
3. The conversion of ozone, 2 O3 (g) → 3 O2 (g), obeys the rate law, rate = k [O3]2[O2]−1. Which of the following statements is true regarding the rate of the breakdown of ozone (O3) into molecular oxygen (O2)?
4. All of the following result in an increased rate of reaction in an aqueous solution except:
5. Doubling the concentration of M and N increases the reaction rate by eight fold. Halving the concentration of N decreases the reaction rate four fold.
6. Factors that affect the rate at which a chemical reaction proceeds include which of the following? I. The orientation of the reactants at time of collision II. The kinetic energy of the collisions between reactants III. The frequency of collisions between reactants
7. The reaction of nitric oxide with hydrogen gas at 25°C and 1 atm is represented below. The rate law for this reaction is: rate = k [H2][NO]2. According to the rate law, which of the following is the best prediction of the rate of this reaction?
8. The reaction between nitrogen dioxide and carbon monoxide is represented above. The proposed reaction mechanism is as follows: Which of the following reaction mechanisms is consistent with the proposed mechanism?
9. Doubling the concentration of M only quadruples the reaction rate.
10. Which of the following can be used to calculate or measure the rate of a chemical reaction? I. The appearance of product over time II. The disappearance of one or more substrates over time III. The rate law IV. The Keq (equilibrium constant) and Q (reaction quotient) of the reaction
11. All of the following statements regarding the kinetics of radioactive decay are true except:
12. Which of the following correctly explain(s) the effect of increased temperature on the rate of a chemical reaction? I. Increases the reaction rate of endothermic reactions II. Increases the reaction rate of exothermic reactions III. Decreases the reaction rate of reactions with a –ΔH
13. All of the following statements regarding the activated complex are true except:
14. A chemistry student sitting around a campfire observes that the large pieces of wood burn slowly, but a mixture of small scraps of wood and sawdust added to the flame combusts explosively. The correct explanation for the difference in the combustion between these two forms of wood is that, compared with the wood scraps and sawdust, the large pieces of wood
15. Doubling the concentration of M and N increases reaction rate by 2.
16. The reaction between nitrogen monoxide (commonly called nitric oxide) and bromine is represented above. The proposed reaction mechanism is as follows: Which of the following reaction mechanisms is consistent with the proposed mechanism?
17. The production of iron (II) sulfide occurs at a significantly higher rate when iron filings are used instead of blocks (volume = 0.1 mL). Which of the following best explains this observation?
18. The rate constant for a certain chemical reaction at 25°C is 9.0 × 105 L2mol−2sec−1. Which of the following must be true regarding this reaction?
19. The rate laws for the reaction between O2 and NO is k = [O2][NO]2. If the reaction rate is first measured with O2 and NO of 2.5 × 10−4 M each, by what factor will the rate increase if the concentration of O2 and NO are both increased to 5.0 × 10−4 each?
20. Doubling the concentration of M has no effect on the reaction rate.